Hello @Nageshk and welcome to the ST Community 😊.
If you arr looking for the JTAG/SWD Debug pins. You have just to look for the JNTRST pin is PB4, JTDI pin is PA15, JTDO pin is PB3, JTMS/SWDIO pin is PA13 and JTCK/SWCLK pin is PA14. They are available on the
Table 5. Medium-density STM32F103xx pin definitions of the DS5319.
Best Regards.
STTwo-32
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