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I have RS-485 transceiver connected to USART1 (PA9 + PA10) and relay connected to PB4. If MCU have erased FLASH or RST-pin connected to GND all incoming data to pin PA10 (Rx) for RS-485 line translated to pin PB4 in inversion (0 on PA10 => 1 on PB4, ...
On my board i use USART1 and USART3 to connect my device to other by dual RS-485. 485 tranciever connected to MCU throw digital isolator (4 tx, 2 rx SI8662). If 485 line of USART1 not connected ti device i can start debugging in Keil without problem....