Hello Vaibh_p,
There is no procedure to measure the tags resonance while reading the tag using the NFC reader.
Generally we are using a ISO calibration coil and S11 measurement. Also any other coil - like wire wound antennas can be taken.
You then have to setup the VNA to do a S11 measurement and do a short calibration of the attached antenna. Afterwards you can put it close to the tag and measure its resonance frequency and Q-factor.
Changing the output power, you can simulate a different field strength. Typically the VNA can be changed between 10dBm and -30dBm output power.
You can then also bring the unpowered reader into the field and see how reader and tag are impacting each other or which influence the metal has.
If the metal is always there when reading the tag, then the reader (or tags resonance) can also be tuned with this metal in proximity.
BF Travis